Lipase-Catalyzed Synthesis and Characterization of 6-O-(11-Dodecenoic)-Glucose Ester in Ionic Liquids
نویسندگان
چکیده
Novozym-435 Lipase-catalyzed transesterification of glucose with 11-dodecenoic ethyl ester in ionic liquids was investigated. The effect of substrate ratio, lipase content, and temperature on the activity and stability of lipase was also studied. The highest yield of sugar ester was obtained in 1-buty-3-methyl imidazolium tetrafluoroborate [Bmim][BF4] under such conditions as the reaction temperature of 55 ̊C,the enzyme concentration of 20 mg/mL,the mole ratio of glucose/11-dodecenoic ethyl ester of 1:2, the water content of the system of 2%, Lipase Novozym-435 can use repeatedly 7 times.The structure of production was characterized by FTIR, HPLC, MS and NMR. The results show that the production is 6-O-(11-dodecenoic)-glucose ester.
منابع مشابه
Efficient and eco-friendly synthesis of quinoxalines derivatives catalyzed by acidic ionic liquids at room temperature
In this research, we have developed cheap recyclable and task-specific acidic ionic liquids (AILs) 1-hydrogen-3-methylimidazolium hydrogen sulfate [Hmim]HSO4, 1-hydrogen-3-methylimidazolium chloride [Hmim]Cl, 2-pyrrolidonium hydrogensulfate [Hnhp]HSO4 and applied them in acid catalyzed synthesis of quinoxaline derivatives from 1,2-phenylendiamines and 1,2-dicarbonyl compounds. The products coul...
متن کاملEfficient and eco-friendly synthesis of quinoxalines derivatives catalyzed by acidic ionic liquids at room temperature
In this research, we have developed cheap recyclable and task-specific acidic ionic liquids (AILs) 1-hydrogen-3-methylimidazolium hydrogen sulfate [Hmim]HSO4, 1-hydrogen-3-methylimidazolium chloride [Hmim]Cl, 2-pyrrolidonium hydrogensulfate [Hnhp]HSO4 and applied them in acid catalyzed synthesis of quinoxaline derivatives from 1,2-phenylendiamines and 1,2-dicarbonyl compounds. The products coul...
متن کاملMixture of Ionic Liquids as Novel Media for Green Synthesis of Diketopyrrolopyrrole Pigments
A green method for the synthesis of high-performance diketopyrrolopyrrole pigments using diethyl succinate in the presence of mixture of ionic liquids is reported. Although, alkaline condition is needed in the succinate ester route for synthesis of the pigments, in the present study, the replacement possibility of conventional organic base by mixture of BMIMOH and BMIMBF4 ionic liquids was inve...
متن کامل1-(1-Propylsulfonic)-3-methylimidazolium chloride Brønsted acidic ionic liquid catalyzed one-pot synthesis of 14-aryl-14H-dibenzo[a,j]xanthene derivatives under solvent-free conditions
A rapid, green and efficient method for the synthesis of 14-aryl-14H-dibenzo[a,j]xanthene derivatives through a one-pot condensation of 2-naphthol with various aromatic aldehydes in the presences of several acidic ionic liquids including [PSMIM]Cl, [BMIM]HSO4, [BMIM]Cl, [BMIM]Br, and [BMIM]BF4 as organocatalysts and task-specific acidic ionic liquids (AILs) under solvent-free conditions is desc...
متن کامل1-(1-Propylsulfonic)-3-methylimidazolium chloride Brønsted acidic ionic liquid catalyzed one-pot synthesis of 14-aryl-14H-dibenzo[a,j]xanthene derivatives under solvent-free conditions
A rapid, green and efficient method for the synthesis of 14-aryl-14H-dibenzo[a,j]xanthene derivatives through a one-pot condensation of 2-naphthol with various aromatic aldehydes in the presences of several acidic ionic liquids including [PSMIM]Cl, [BMIM]HSO4, [BMIM]Cl, [BMIM]Br, and [BMIM]BF4 as organocatalysts and task-specific acidic ionic liquids (AILs) under solvent-free conditions is desc...
متن کامل